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The
University Lecturer in Chemistry 1998-1999
Robert
W. Field
Robert
T. Haslam and Bradley Dewey Professor of Chemistry
Massachusetts
Institute of Technology
Professor
Robert W. Field is a distinguished molecular spectroscopist. He has developed
a variety of laser spectroscopic techniques to examine the electronic
and vibrational spectra of small, gas phase molecules. These techniques
include Microwave Optical Double Resonance, Optical Optical Double Resonance,
Optically Pumped Electronic Transition Lasers, Modulated Gain Spectroscopy,
Perturbation Facilitated Optical Optical Double Resonance, Stimulated
Emission Pumping ("Pump and Dump"), Frequency Modulation Enhanced Magnetic
Rotation Spectroscopy, Sideband Optical Optical Double Resonance Zeeman
Spectroscopy, and Optical Optical Microwave Triple Resonance Spectroscopy.
Armed with these experimental techniques as well as powerful pattern recognition
schemes such as Extended Spectral Cross Correlation, it has been possible
to extract information from unprecedentedly complex spectra. He has shown
that often it is the most complicated spectra that open a window into
elegantly simple insights into the structure and dynamics of a molecule.
Two of his favorite phrases are "beyond molecular constants" and "dynamics
encoded in frequency domain spectra." Starting with his pioneering studies
of spectroscopic perturbations, he has developed a series of increasingly
comprehensive zero-order pictures of molecular structure that provide
mechanistic insights into the early time dynamics of a wide variety of
intramolecular processes: where is the excitation initially localized,
where does it go first, how fast, why?
Professor Field was
born on June 13, 1944 in Wilmington, Delaware. He graduated magna cum
laude from Amherst College in 1965 where he had his first experience
of spectroscopy in his A.B. thesis research with Professor Cooper H. Langford.
Then, supervised by Professor William Klemperer at Harvard University,
he gained his initial experience with multiple resonance spectroscopies
and spectroscopic perturbations (of CO). After receiving his Ph.D. in
Physical Chemistry in 1971, he did postdoctoral research with Professor
Herbert P. Broida and Professor David O. Harris at the University of California
Santa Barbara. At UCSB, he became a "laser spectroscopist" and recorded
the first laser-microwave Microwave-Optical Double Resonance (MODR) and
laser-laser Optical-Optical Double Resonance (OODR) spectra of molecules
(BaO). In 1974 he began his academic career at the Massachusetts Institute
of Technology, becoming Professor in 1982 and the Robert T. Haslam and
Bradley Dewey Professor of Chemistry in 1999.
Professor Field has
received may awards and honours as a result of his distinguished research
in Molecular Spectroscopy and Dynamics. He was awarded the H.P. Broida
Prize (1980) and the E.K. Plyler Prize (1988) from the American Physical
Society, the Ellis Lippincott Award (1990) and William F. Meggers Award
(1996) from the Optical Society of America, and as co-preceptor with Professor
James L. Kinsey of Dr. Yongqin Chen, the Nobel Laureate Signature Award
of the American Chemical Society (1990) for the best Ph.D. thesis of the
year. He received an honorary doctorate from his alma mater, Amherst
College, in 1997 and was elected to the American Academy of Arts and Sciences
in 1998. He has served on the editorial advisory boards of The Journal
of Chemical Physics, The Journal of Physical Chemistry, Annual
Reviews of Physical Chemistry, Chemical Physics Letters, and
The Journal of Molecular Spectroscopy. He is the author of more
than 270 papers, co-author (with Hélène Lefebvre-Brion)
of Perturbations in the Spectra of Diatomic Molecules, and co-editor
of Molecular Dynamics and Spectroscopy by Stimulated Emission Pumping
and Nonlinear Spectroscopy for Molecular Structure Determination.
He has supervised the Ph.D. research of 35 students.
Professor Field will
present three lectures during his visit to UWO:
Tuesday, October 12,
1999 4:00 p.m.
Putting the Periodic Table Back into Molecular Electronic Structure:
Atomic Ions in Diatomic Molecules
Wednesday, October 13,
1999 4:00 p.m.
Core-Nonpenetrating Rydberg States are Spectroscopic Black Holes: Molecular
Ions in Molecules
Thursday, October
14, 1999 4:00 p.m.
Acetylene at the
Threshold of Isomerization
All Lectures will
be given
in Room 193, Medical
Sciences
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